A New Protocol for the Synthesis of New Thioaryl-Porphyrins Derived from 5,10,15,20-Tetrakis(pentafluorophenyl)porphyrin: Photophysical Evaluation and DNA-Binding Interactive Studies

Autor:	Patrícia Foletto, Fabiula Correa, Luciano Dornelles, Bernardo A. Iglesias, Carolina H. da Silveira, Pablo A. Nogara, João B. T. da Rocha, Maria A. F. Faustino, Oscar E. D. Rodrigues
Jazyk:	angličtina
Rok vydání:	2018
Předmět:	thioaryl-porphyrins disulfides DNA interaction photophysical characterization Organic chemistry QD241-441
Zdroj:	Molecules, Vol 23, Iss 10, p 2588 (2018)
Druh dokumentu:	article
ISSN:	1420-3049
DOI:	10.3390/molecules23102588
Popis:	A new protocol for the preparation of thioaryl-porphyrins is described. The compounds were prepared from different disulfides employing NaBH4 as a reducing agent. The methodology allowed the preparation of four different thioaryl-porphyrins in very-good to excellent yields under soft conditions, such as short reaction times and smooth heating. Additionally, the photophysical properties of new compounds were determined and experimental and theoretical DNA interactions were assessed.
Databáze:	Directory of Open Access Journals
Externí odkaz:	https://doaj.org/article/96fd043718c34c62811a0f56dcf49f9e Zobrazit plný text záznamu View record in DOAJ Plný text ve formátu PDF Plný text ve formátu HTML
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