A New Organic Conductor of Tetramethyltetraselenafulvalene (TMTSF) with a Magnetic Dy(III) Complex

Autor: Qingyun Wan, Masanori Wakizaka, Haitao Zhang, Yongbing Shen, Nobuto Funakoshi, Chi-Ming Che, Shinya Takaishi, Masahiro Yamashita
Jazyk: angličtina
Rok vydání: 2023
Předmět:
Zdroj: Magnetochemistry, Vol 9, Iss 3, p 77 (2023)
Druh dokumentu: article
ISSN: 2312-7481
DOI: 10.3390/magnetochemistry9030077
Popis: A new molecular conductor of (TMTSF)5[Dy(NCS)4(NO3)2]CHCl3 was prepared using the electrochemical oxidation method. The complex crystallizes in the Cmc21 (36) space group, where the partially-oxidized TMTSF molecules form a 1D (one-dimensional) column structure. The crystal shows a semiconducting behavior with a room temperature conductivity of 0.2 S·cm−1 and an activation energy of 34 meV at ambient pressure.
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