A short stereoselective synthesis of (+)-(6R,2′S)-cryptocaryalactone via ring-closing metathesis

Autor: Palakodety Radha Krishna, Krishnarao Lopinti, K. L. N. Reddy
Jazyk: angličtina
Rok vydání: 2009
Předmět:
Zdroj: Beilstein Journal of Organic Chemistry, Vol 5, Iss 1, p 14 (2009)
Druh dokumentu: article
ISSN: 1860-5397
DOI: 10.3762/bjoc.5.14
Popis: A short stereoselective synthesis of (+)-(6R,2′S)-cryptocaryalactone was successfully completed. Key steps included the application of Carreira’s asymmetric alkynylation reaction to form a propargylic alcohol and subsequently lactone formation using the powerful ring-closing metathesis reaction.
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