ZnCl2-Enhanced Intrinsic Luminescence of Tin Chlorophosphate Glasses

Autor: Ting Wu, Yiting Tao, Panting Wang, Mingjun Zhao, Danping Chen
Jazyk: angličtina
Rok vydání: 2022
Předmět:
Zdroj: Photonics, Vol 9, Iss 12, p 973 (2022)
Druh dokumentu: article
ISSN: 2304-6732
DOI: 10.3390/photonics9120973
Popis: This communication reports the intrinsic luminescence of tin chlorophosphate glasses. The glass maintains the low melting point characteristics of tin fluorophosphate glasses, and exhibits a red-shifted and broadened excitation wavelength peak. Tin chlorophosphate glasses can exhibit a broadband luminescence of 400–700 nm under an excitation of 380–430 nm. Furthermore, the introduction of ZnCl2 into tin chlorophosphate glasses can considerably enhance the luminescence without affecting their low-melting characteristics. The luminescence intensity can be increased fourfold, with the enhancement attributed to the reduced visible absorption, improved dispersion of Sn2+ ions, and the energy exchange between Sn2+ and Zn2+ in the glasses owing to the addition of ZnCl2.
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