Nano copper oxide catalyzed synthesis of symmetrical diaryl sulfides under ligand free conditions

Autor: K. Harsha Vardhan Reddy, V. Prakash Reddy, A. Ashwan Kumar, G. Kranthi, Y.V.D. Nageswar
Jazyk: angličtina
Rok vydání: 2011
Předmět:
Zdroj: Beilstein Journal of Organic Chemistry, Vol 7, Iss 1, Pp 886-891 (2011)
Druh dokumentu: article
ISSN: 1860-5397
DOI: 10.3762/bjoc.7.101
Popis: Potassium thiocyanate acts as an efficient sulfur surrogate in C–S cross-coupling reactions mediated by recyclable copper oxide nanoparticles under ligand free conditions. This protocol avoids foul smelling thiols, for the synthesis of a variety of symmetrical diaryl sulfides, via the cross-coupling of different aryl halides with potassium thiocyanate, affording corresponding products in moderate to excellent yields.
Databáze: Directory of Open Access Journals