Hyperthermal velocity distributions of recombinatively-desorbing oxygen from Ag(111)

Autor: Arved C. Dorst, Rasika E. A. Dissanayake, Daniel Schauermann, Sofie Knies, Alec M. Wodtke, Daniel R. Killelea, Tim Schäfer
Jazyk: angličtina
Rok vydání: 2023
Předmět:
Zdroj: Frontiers in Chemistry, Vol 11 (2023)
Druh dokumentu: article
ISSN: 2296-2646
DOI: 10.3389/fchem.2023.1248456
Popis: This study presents velocity-resolved desorption experiments of recombinatively-desorbing oxygen from Ag (111). We combine molecular beam techniques, ion imaging, and temperature-programmed desorption to obtain translational energy distributions of desorbing O2. Molecular beams of NO2 are used to prepare a p (4 × 4)-O adlayer on the silver crystal. The translational energy distributions of O2 are shifted towards hyperthermal energies indicating desorption from an intermediate activated molecular chemisorption state.
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