| Autor: |
DARKO HANZEL, VENCESLAV KAUCIC, DJORDJE STOJAKOVIC, NEVENKA RAJIC |
| Jazyk: |
angličtina |
| Rok vydání: |
2004 |
| Předmět: |
|
| Zdroj: |
Journal of the Serbian Chemical Society, Vol 69, Iss 3, Pp 179-185 (2004) |
| Druh dokumentu: |
article |
| ISSN: |
0352-5139 |
| Popis: |
1,3-Diaminopropane (DAP) was used as a structure-directing agent for the hydrothermal synthesis of an organically templated iron phosphate. During crystallization at 180 ºC, iron phosphate (FePO-DAP) with a layered structure was formed after one day. Longer crystallization yielded a mixture of FePO-DAP and leucophosphite, raising the question whether a transformation of FePO-DAP to leucophosphite occurs, or wheter DAP decomposes under hydrothermal conditions resulting in leucophosphite formation. Lattice energy and free energy calculations strongly support the supposition that a decomposition of DAP occurs prior to the formation of leucophosphite. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
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