A new organic–inorganic compound, ethylenediammonium hexachloridostannate(IV) p-anisaldehyde disolvate
| Autor: | Adrienne Ndiolene, Tidiane Diop, Mouhamadou Sembène Boye, Aminata Diasse-Sarr, Ulli Englert |
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| Jazyk: | angličtina |
| Rok vydání: | 2021 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E: Crystallographic Communications, Vol 77, Iss 7, Pp 696-699 (2021) |
| Druh dokumentu: | article |
| ISSN: | 2056-9890 20569890 |
| DOI: | 10.1107/S205698902100579X |
| Popis: | The asymmetric unit of the title organic–inorganic hybrid complex [systematic name: ethane-1,2-diaminium hexachloridostannate(IV)–4-methoxybenzaldehyde (1/2)], (C2H10N2)[SnCl6]·2C8H8O2, contains one half of an ethylenediammonium cation, one half of an [SnCl6]2− anion and one p-anisaldehyde molecule. Both the organic cation and the quasi-regular octahedral inorganic anion are located about inversion centres. The organic cations and [SnCl6]2− anions lie in layers parallel to the ac plane with p-anisaldehyde molecules occupying the space between the layers. A network of classical N—H...Cl and N—H...O hydrogen bonds exists between the ethylenediammonium cations and the [SnCl6]2− anions and p-anisaldehyde molecules. These interactions, together with non-classical C—H...O interactions between the ethylenediammonium cations and the p-anisaldehyde molecules, serve to hold the structure together. The crystal studied was refined as a two-component twin. |
| Databáze: | Directory of Open Access Journals |
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