An alternative derivation of (almost-) Watson’s Hamiltonian
| Autor: | Perić Miljenko |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2013 |
| Předmět: | |
| Zdroj: | Journal of the Serbian Chemical Society, Vol 78, Iss 12, Pp 1935-1962 (2013) |
| Druh dokumentu: | article |
| ISSN: | 0352-5139 1820-7421 |
| DOI: | 10.2298/JSC131109107P |
| Popis: | A derivation of the general wave-mechanical Hamiltonian for non-linear molecules is presented. It is based on the transformation of proper classical (Hamilton) moment into their wave-mechanical counterparts by means of the Podolsky transformation in its original form. The result is essentially identical to that obtained by Watson in his milestone paper [J.K.G. Watson, Mol. Phys. 15 (1968) 479]. While not so elegant as that of the original reference, the way proposed in the present study is conceptually much simpler. This procedure can be applied to other types of molecular Hamiltonians too. [Projekat Ministarstva nauke Republike Srbije, br. 172040] |
| Databáze: | Directory of Open Access Journals |
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