| Autor: |
Abhishikta Chatterjee, Laurence K. Thompson, Subrata K. Dey |
| Jazyk: |
angličtina |
| Rok vydání: |
2018 |
| Předmět: |
|
| Zdroj: |
Magnetochemistry, Vol 4, Iss 4, p 53 (2018) |
| Druh dokumentu: |
article |
| ISSN: |
2312-7481 |
| DOI: |
10.3390/magnetochemistry4040053 |
| Popis: |
The iron (II) coordination compound, {[Fe(3,6 pzdc)](H2O)2}2. (1) has been synthesized from a mixture of FeCl2.4H2O and pyridazinedicarboxylate (3,6 pzdc). The molecular structure of complex 1 was determined by single crystal X-ray diffraction study. It reveals that the dinuclear structure contains a pyridazine bridge in between the two metal centers. The variable temperature magnetic study results in g = 2.496(8), J = −2.50(8) cm−1, Ɵ = −0.1 K values, by fitting the magnetic data in a simple dinuclear Fe-Fe model which indicates that the major exchange pathway through the N-N bridge. Presence of dense H-bonding interaction leads to supramolecular network formation. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
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