Poly[μ2-aqua-μ4-naphthalene-1,8-dicarboxylato-manganese(II)]
| Autor: | Guo-Ying Zhang, Xin Zhang, Gui-Sheng Yu |
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| Jazyk: | angličtina |
| Rok vydání: | 2008 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 64, Iss 1, Pp m214-m214 (2008) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S1600536807063696 |
| Popis: | The asymmetric unit of the title complex, [Mn(C12H6O4)(H2O)]n, contains one MnII ion, one 1,8-naphthalenedicarboxylate (1,8-NDC) ligand and one water molecule. The MnII ion is six-coordinated within a distorted octahedral coordination geometry, in which the equatorial sites are occupied by four carboxylate O atoms from four different 1,8-NDC ligands, while the axial positions are occupied by two O atoms of two coordinated water molecules. Adjacent MnII centres are bridged by one coordinated water and two carboxylate groups in a syn–syn mode to form infinite chains along the b axis, which are further cross-linked by the naphthalene spacers of the 1,8-NDC ligands to produce a two-dimensional extended network. |
| Databáze: | Directory of Open Access Journals |
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