High-Pressure Hydrogenation: A Path to Efficient Methane Production from CO2

Autor: Maitê L. Gothe, Adolfo L. Figueredo, Laís R. Borges, Ruben Ramos, Andreia F. Peixoto, Pedro Vidinha
Jazyk: angličtina
Rok vydání: 2024
Předmět:
Zdroj: Methane, Vol 3, Iss 1, Pp 53-64 (2024)
Druh dokumentu: article
ISSN: 2674-0389
DOI: 10.3390/methane3010004
Popis: Methane has a rather relevant role in the “Power-to-Gas” concept, which is central in the current paradigm of climate change and renewable energies. Methane, the main component of natural gas, can be produced by catalytic hydrogenation reactions, particularly of CO2. A very effective catalyst in this reaction, hydrotalcite-derived nickel nanoparticles supported on alumina, Ni/Al2O3-HTC, can be employed in a high-pressure flow reactor to convert CO2 and H2 into CH4 at 100% selectivity and 84% conversion, whereas at atmospheric pressure, methane can be obtained with up to 90% selectivity. The high-pressure aspect also allows fast-paced production—over 5 m3·h−1·kgcat−1 of CH4 can be generated.
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