V3S4 Nanosheets Anchored on N, S Co-Doped Graphene with Pseudocapacitive Effect for Fast and Durable Lithium Storage

Autor: Naiteng Wu, Di Miao, Xinliang Zhou, Lilei Zhang, Guilong Liu, Donglei Guo, Xianming Liu
Jazyk: angličtina
Rok vydání: 2019
Předmět:
Zdroj: Nanomaterials, Vol 9, Iss 11, p 1638 (2019)
Druh dokumentu: article
ISSN: 2079-4991
DOI: 10.3390/nano9111638
Popis: Construction of a suitable hybrid structure has been considered an important approach to address the defects of metal sulfide anode materials. V3S4 nanosheets anchored on an N, S co-coped graphene (VS/NSG) aerogel were successfully fabricated by an efficient self-assembled strategy. During the heat treatment process, decomposition, sulfuration and N, S co-doping occurred. This hybrid structure was not only endowed with an enhanced capability to buffer the volume expansion, but also improved electron conductivity as a result of the conductive network that had been constructed. The dominating pseudocapacitive contribution (57.78% at 1 mV s−1) enhanced the electrochemical performance effectively. When serving as anode material for lithium ion batteries, VS/NSG exhibits excellent lithium storage properties, including high rate capacity (480 and 330 mAh g−1 at 5 and 10 A g−1, respectively) and stable cyclic performance (692 mAh g−1 after 400 cycles at 2 A g−1).
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