| Autor: |
Eya Toumi, Nour Elleuch, Sergiu Shova, Mohamed Boujelbene |
| Jazyk: |
angličtina |
| Rok vydání: |
2024 |
| Předmět: |
|
| Zdroj: |
Results in Chemistry, Vol 12, Iss , Pp 101879- (2024) |
| Druh dokumentu: |
article |
| ISSN: |
2211-7156 |
| DOI: |
10.1016/j.rechem.2024.101879 |
| Popis: |
A novel 0D organic–inorganic hybrid antimony-based halide [((R)-C8H12N)4](Sb2Cl10) was achieved through a slow evaporation method at room temperature. Single crystal X-ray diffraction analysis revealed that the compound crystallizes in the monoclinic system, within the P21 space group. The structure consists of(R)-1-phenylethylammonium (C8H12N)+cations and [Sb2Cl10]4− dimers, formed by edge-sharing distorted octahedra. The cohesion of the structure were ensured by N-H…Cl hydrogen bonds. Hirshfeld surface analysis indicated H…H interactions as the dominant intermolecular interaction contacts (42.4 %). Infrared and Raman spectroscopy confirmed the presence of organic cations and inorganic components. The thermogravimetric analysis demonstrated that the compound exhibits thermal stability up to 180 °C. Finally, Optical studies further suggest that this material holds significant promise for optical and optoelectronic applications. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
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