Synergistic improvement of mechanical, electrical and thermal properties by graphene nanoplatelets in polyaniline incorporated rubbery thermoplastic composites

Autor: Farrah Diyana Zailan, Ruey Shan Chen, Sahrim Haji Ahmad, Moayad Husein Flaifel, Dalila Shahdan, Wan Nazri Wan Busu, Lih Jiun Yu
Jazyk: angličtina
Rok vydání: 2024
Předmět:
Zdroj: Journal of Materials Research and Technology, Vol 28, Iss , Pp 4097-4109 (2024)
Druh dokumentu: article
ISSN: 2238-7854
DOI: 10.1016/j.jmrt.2024.01.018
Popis: Here, thermoplastic natural rubber (TPNR) blend filled with polyaniline (PANi) and graphene nanoplatelets (GNPs) was fabricated via melt blending and compression moulding. The synergistic influence of including 1–5 wt% GNPs with 3 wt% PANi in nanocomposites on the mechanical via tensile test, Impedance electrical test, thermal stability via thermogravimetric analysis test and morphologic observation were examined. Inclusion of 2 wt% of GNPs increased by 62.8 % on tensile strength and 151.8 % on Young's modulus of TPNR/PANi. The highest electrical conductivity and thermal stability were achieved in the same nanocomposite composition. With a low loading of GNPs, an electrical conductivity of 2.6 E−9 S/cm was achieved which potential to be a new semi-conductive material. At this optimum content, the scanning electron microscopy micrograph revealed a homogenous distribution of GNPs in the TPNR/PANi blend as well as good matrix-filler interaction. To be practical in real application, cost-effectiveness is another important aspect to be determined. In this work, researchers evaluated the cost-performance of each system (TPNR, TPNR/PANi and TPNR/PANi/GNP) based on material costs, mechanical and electrical properties. Different general trends (positive, negative and synergistic) of cost-efficiency relationship were obtained for different material system and the priority greatly depends on their intended uses.
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