| Autor: |
Marisela Reyes, Lenis Prado, Bernardo Fontal, Trino Suárez, Fernando Bellandi, Yuraima Fonseca, Pedro Cancines |
| Jazyk: |
English<br />Spanish; Castilian |
| Rok vydání: |
2009 |
| Předmět: |
|
| Zdroj: |
Avances en Química, Vol 4, Iss 2, Pp 79-82 (2009) |
| Druh dokumentu: |
article |
| ISSN: |
1856-5301 |
| Popis: |
Catalytic naphtha hydroformylation with Rh and Mo complexes in biphasic medium. Parameter optimization. The Chlorocarbonyl bis-(diphenyl[meta-sulphonate of sodium phenyl]phosphine)Rhodium(I) [RhCl(CO)[P(C6H6)2(m-(C6H5)SO3Na)]2], Chlorocarbonyl bis-(phenyl[meta-sulphonate of sodium diphenyl]phosphine)Rhodium(I) [RhCl(CO)[P(C6H6)(m-(C6H5)SO3Na)2]2] and Tetracarbonyl bis-[para-pyridine sulphonate of sodium] Molybdenum (0) [Mo(CO)4(p-(NC5H4)SO3Na)2] (TPPMS Triphenylphosphine Monosulphonate = [P(C6H6)2 (m-(C6H5)SO3Na)] (TPPDS= Triphenylphosphine meta-disulphonate = [P(C6H6)(m-(C6H5)SO3Na)2] and pySO3Na= para-Pyridine sulphonate of sodium = [p-(NC5H4)SO3Na] complexes were used as catalytic precursors in the catalytic hydroformylation of real naphtha in biphasic organic/water medium. With complexes (1) and (2) there is a good conversion of olefins to medium sized linear and substituted aldehydes and alcohols, and with complex (3) not catalytic activity in hydroformylation reactions of light naphtha was observed. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
|
