Nano-laminated BN modified graphite reinforced unfired MgO–C refractories: Preparation, properties and strengthening mechanism

Autor: Shutong Fan, Chengji Deng, Chao Yu, Zhenglong Liu, Jun Ding
Jazyk: angličtina
Rok vydání: 2024
Předmět:
Zdroj: Journal of Materials Research and Technology, Vol 29, Iss , Pp 4833-4844 (2024)
Druh dokumentu: article
ISSN: 2238-7854
DOI: 10.1016/j.jmrt.2024.02.201
Popis: To solve the problem of deterioration of oxidation resistance and thermal shock resistance caused by low carbonization of MgO–C refractories, nano-laminated BN modified graphite was prepared by the molten salt method to reinforce unfired MgO–C refractories. The findings revealed that the introduction of nano-laminated BN modified graphite significantly improved the mechanical properties. Moreover, the oxidation index of MgO–C refractories with 4 wt% nano-laminated BN modified graphite was 34% lower than that of the unadded sample, and the residual strength after thermal shock was significantly increased by 224%. Furthermore, incorporating nano-laminated BN modified graphite facilitated the formation of columnar Mg2SiO4, octagonal columnar MgAl2O4, and MgO–Mg2SiO4–MgAl2O4–Mg3B2O6 dense layers, thereby contribute to overall performance improvements.
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