| Autor: |
M. Das, S. Pal, K. Naskar |
| Jazyk: |
angličtina |
| Rok vydání: |
2020 |
| Předmět: |
|
| Zdroj: |
eXPRESS Polymer Letters, Vol 14, Iss 9, Pp 860-880 (2020) |
| Druh dokumentu: |
article |
| ISSN: |
1788-618X |
| DOI: |
10.3144/expresspolymlett.2020.71 |
| Popis: |
Dynamic covalent crosslinking such as disulfide bonds, Diels-Alder (DA) reactions are widely used for healing applications. Herein, we report a simple approach involving the metal-ligand reversible interactions in diverse nature, which helps in developing a robust and self-healable carboxylated nitrile (XNBR) rubber by employing low cost and the commercially obtainable materials. Self-healing performance and mechanical properties were organized by introducing the various metal-ligand domains into the XNBR rubber. The network of XNBR, in-situ cross-linked via metal-ligand complexes, consists of strong and weak coordination bonds. The strength of various metal-ligand modified coordination bonds, healing performance, and mechanical properties primarily depend on the type of metal ions. The Fourier transform infrared spectroscopy (FTIR) makes the various metal-ligand coordination bond formation into the XNBR rubber visible. The coordination crosslinked XNBR rubber with 4 phr of Zn and Co metal ion exhibits high tensile strength (4.3±0.6 and 10.3±1.1 MPa) with excellent healing efficiency (100 and 88%), which is far higher than the most reported non-covalent supramolecular modified elastomers. The various metal-ligand coordination bonds are fully reconstructed during the rebuilding process and exhibiting excellent self-healing property. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
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