| Autor: |
Yue Zhong, Wen-Yu Wu, Shao-Peng Yu, Tian-Yuan Fan, Hai-Tao Yu, Nian-Guang Li, Zhi-Hao Shi, Yu-Ping Tang, Jin-Ao Duan |
| Jazyk: |
angličtina |
| Rok vydání: |
2019 |
| Předmět: |
|
| Zdroj: |
Beilstein Journal of Organic Chemistry, Vol 15, Iss 1, Pp 291-298 (2019) |
| Druh dokumentu: |
article |
| ISSN: |
1860-5397 |
| DOI: |
10.3762/bjoc.15.26 |
| Popis: |
Herein we report a novel palladium-catalyzed reaction that results in phenanthrene derivatives using aryl iodides, ortho-bromobenzoyl chlorides and norbornadiene in one pot. This dramatic transformation undergoes ortho-C–H activation, decarbonylation and subsequent a retro-Diels–Alder process. Pleasantly, this protocol has a wider substrate range, shorter reaction times and higher yields of products than previously reported methods. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
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