Bis[4-amino-N-(pyrimidin-2-yl-κN)benzenesulfonamidato-κN](4,4′-dimethyl-2,2′-bipyridine-κ2N,N′)cadmium dimethylformamide disolvate
| Autor: | G. M. Golzar Hossain, A. J. Amoroso |
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| Jazyk: | angličtina |
| Rok vydání: | 2012 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 68, Iss 3, Pp m276-m277 (2012) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S1600536812004412 |
| Popis: | In the title compound, [Cd(C10H9N4O2S)2(C12H12N2)]·2C3H7NO, the CdII ion lies on a twofold rotation axis, is six-coordinated by N atoms, and displays a trigonal–prismatic geometry arising from the two sulfadiazinate ligands and one 4,4′-dimethyl-2,2′-bipyridine ligand. Both ligands are bidentate and coordinate via their N atoms. The O and carbonyl C atoms of the dimethylformamide molecule show disorder and were modelled with two different orientations and with site occupancies of 0.584 (10):0.416 (10). The geometry around the sulfadiazine S atom is distorted tetrahedral. The crystal structure involves N—H...O hydrogen bonds which link molecules into a three-dimensional network. Weak C—H...O hydrogen bonds are also observed. |
| Databáze: | Directory of Open Access Journals |
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