Anomalous Behavior in the Atomic Structure of Nb3Sn under High Pressure

Autor: Irene Schiesaro, Simone Anzellini, Rita Loria, Raffaella Torchio, Tiziana Spina, René Flükiger, Tetsuo Irifune, Enrico Silva, Carlo Meneghini
Jazyk: angličtina
Rok vydání: 2021
Předmět:
Zdroj: Crystals, Vol 11, Iss 4, p 331 (2021)
Druh dokumentu: article
ISSN: 2073-4352
DOI: 10.3390/cryst11040331
Popis: In the present study, the local atomic structure of a Nb3Sn superconductor sample has been probed by X-ray absorption fine structure (XAFS) as a function of hydrostatic pressure (from ambient up to 26 GPa) using a diamond anvil cell set-up. The analysis of the Nb-K edge extended X-ray absorption fine structure (EXAFS) data was carried out combining standard multi shell structural refinement and reverse Monte Carlo method to provide detailed in situ characterization of the pressure-induced evolution of the Nb local structure in Nb3Sn. The results highlight a complex evolution of Nb chains at the local atomic scale, with a peculiar correlated displacement of Nb–Nb and Nb–Nb–Nb configurations. Such a local effect appears related to anomalies evidenced by X-ray diffraction in other superconductors belonging to the same A15 crystallographic structure.
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