Enantioselective Total Synthesis of (R,R)-Blumenol B and d9-(R,R)-Blumenol B

Autor:	Shi Min Tan, Shaun W. P. Rees, Rebecca E. Jelley, Jin Wang, Bruno Fedrizzi, David Barker
Jazyk:	angličtina
Rok vydání:	2022
Předmět:	wine aroma C13-norisoprenoids blumenol B isotopic labelling Organic chemistry QD241-441
Zdroj:	Molecules, Vol 27, Iss 21, p 7294 (2022)
Druh dokumentu:	article
ISSN:	1420-3049
DOI:	10.3390/molecules27217294
Popis:	C13-norisoprenoids are of particular importance to grapes and wines, as these molecules influence wine aroma and have been shown to significantly contribute to the distinct character of various wine varieties. Blumenol B is a putative precursor to a number of important wine aroma compounds, including the well-known compounds theaspirone and vitispirane. The enantioselective synthesis of (R,R)-blumenol B from commercially available 4-oxoisophorone was achieved using a short and easily scaleable route, which was then successfully applied to the synthesis of poly-deuterated d9-blumenol B.
Databáze:	Directory of Open Access Journals
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