Carbon-deficient high-entropy (Zr0.17Nb0.2Ta0.2Mo0.2W0.2)C0.89: A potential high temperature and vacuum wear-resistant material

Autor: Jicheng Li, Qiangqiang Zhang, Shuna Chen, Hengzhong Fan, Junjie Song, Yunfeng Su, Litian Hu, Yanchun Zhou, Yongsheng Zhang
Jazyk: angličtina
Rok vydání: 2023
Předmět:
Zdroj: Materials & Design, Vol 226, Iss , Pp 111680- (2023)
Druh dokumentu: article
ISSN: 0264-1275
DOI: 10.1016/j.matdes.2023.111680
Popis: High-entropy carbides are promising materials as sliding structural components in ultra-high temperature environments due to their good phase stability and excellent mechanical properties. However, the tribological behaviors under coupling conditions of high temperature and vacuum environment have not been deeply evaluated. To fill such a gap, the high-temperature tribological properties of carbon-deficient high-entropy (Zr0.17Nb0.2Ta0.2Mo0.2W0.2)C0.89 (HEC0.89) prepared by using five binary carbides (ZrC, NbC, TaC, Mo2C, and WC) as starting materials were investigated. The microhardness and fracture toughness of HEC0.89 were 21.3 ± 0.5 GPa and 4.5 ± 0.2 MPa·m1/2. Most importantly, HEC0.89 exhibited low wear rate (lower than an order of 10-6 mm3/Nm) under vacuum environments from room temperature (RT) to high temperatures. Moreover, the lowest friction coefficient (0.31 ± 0.01) was obtained at 900 °C, which is attributed to the transferring of films consisting of low hardness oxidation products. These results clearly demonstrate the prospective for the application of high-entropy carbides as sliding parts in high-temperature and vacuum environments.
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