| Autor: |
Wieland Kortuz, Sabine Kirschtowski, Andreas Seidel-Morgenstern, Christof Hamel |
| Jazyk: |
angličtina |
| Rok vydání: |
2023 |
| Předmět: |
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| Zdroj: |
Catalysis Communications, Vol 177, Iss , Pp 106633- (2023) |
| Druh dokumentu: |
article |
| ISSN: |
1873-3905 |
| DOI: |
10.1016/j.catcom.2023.106633 |
| Popis: |
For a more resource-efficient production of amines the homogeneously catalyzed tandem hydroaminomethylation reaction is of large relevance. The kinetics of the sulfoxantphos‑rhodium-catalyzed hydroaminomethylation of 1-decene were studied exploiting a thermomorphic solvent system. Focus was a mechanistic kinetic description of the enamine hydrogenation as the final step in the tandem reaction. Based on proposing a catalytic cycle and applying the Christiansen mathematics, a mechanistic rate model was derived and parameterized. The mechanistic model was able to describe the experimental observations in a broad range of operation conditions including pressure and temperature perturbations providing the basis for process design and optimization. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
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Full Text from ScienceDirect