Dichloridobis[2-(1-hydrazinylideneethyl)pyrazine-κN1]zinc
| Autor: | Jia-cheng Liu, Meng Li, Yun Wei, Li-li Liang |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2012 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 68, Iss 5, Pp m710-m710 (2012) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S1600536812016418 |
| Popis: | In the structure of the title complex, [ZnCl2(C6H8N4)2], the ZnII atom has a distorted octahedral geometry. Two cis Cl− ions and four N atoms belonging to two different 2-(1-hydrazinylideneethyl)pyrazine ligands coordinate the ZnII atom, forming two five-membered Zn—N—C—C—N rings. The dihedral angle between the planes of these metallocycles is 88.13 (4)°. The organic ligands are essentially planar (r.m.s. deviations from planarity = 0.072 and 0.040 Å). Intermolecular N—H...N and N—H...Cl interactions join the molecules into a three-dimensional framework. |
| Databáze: | Directory of Open Access Journals |
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