Poly[[bis[μ2-8-ethyl-5-oxo-2-(piperazin-1-yl)-5,8-dihydropyrido[2,3-d]pyrimidine-6-carboxylato]zinc(II)] dihydrate]
| Autor: | Wen Xu, Da-Sheng Zhu, Xiao-Dan Song, Zhe An |
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| Jazyk: | angličtina |
| Rok vydání: | 2009 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 65, Iss 10, Pp m1223-m1223 (2009) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S1600536809036939 |
| Popis: | The title compound, {[Zn(C14H16N5O3)2]·2H2O}n or [Zn(ppa)2]·2H2O}n, where ppa = 8-ethyl-5,8-dihydro-5-oxo-2-(1-piperazinyl)-pyrido(2,3-d)-pyrimidine-6-carboxylate, was synthesized under hydrothermal conditions. The ZnII atom (site symmetry overline{1}) exhibits a distorted trans-ZnN2O4 octahedral geometry defined by two monodentate N-bonded and two bidentate O,O-bonded ppa monoanions. The extended two-dimensional structure arising from this connectivity is a square grid and the disordered uncoordinated water molecules occupy cavities within the grid. An N—H...O hydrogen bond occurs. |
| Databáze: | Directory of Open Access Journals |
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