Crystal structure of tert-butyl-N-phenylcarbonitrilium tetrachloridoaluminate

Autor:	Tom van Dijk, Dirk W. Zant, Robert Wolf, Koop Lammertsma, J. Chris Slootweg
Jazyk:	angličtina
Rok vydání:	2014
Předmět:	crystal structure nitrilium ion tetrachloridoaluminate Crystallography QD901-999
Zdroj:	Acta Crystallographica Section E, Vol 70, Iss 11, Pp 331-333 (2014)
Druh dokumentu:	article
ISSN:	1600-5368 16005368
DOI:	10.1107/S1600536814022028
Popis:	In the title compound, (C11H14N)[AlCl4], the nitrilium (systematic name: 2,2-dimethyl-N-phenylpropanenitrilium) ion adopts a slightly distorted linear configuration [C—N[triple-bond]C = 178.87 (16) and N[triple-bond]C—C = 179.13 (17)°]. In the crystal, while there are no intermolecular hydrogen bonds, pairs of nitrilium ions are linked through π–π interactions [inter–centroid distance = 3.8091 (13) Å].
Databáze:	Directory of Open Access Journals
Externí odkaz:	https://doaj.org/article/d8f5ebf018624d5ca8c3fff0c003d27f Zobrazit plný text záznamu View record in DOAJ