Synthesis of New Pentacyclo[5.4.0.02,6.03,10.05,9]undecane-8,11-dione (PCU) Cyanosilylated Derivatives Using Sulphated Zirconia and Hydrotalcite as Catalysts in Microwave-Assisted Reactions under Solvent Free Conditions

Autor: Juan Navarrete-Bolaños, Rubén Gaviño-Ramírez, Eduardo González-Zamora, Leticia Lomas-Romero, Guillermo E. Negrón-Silva, Deyanira Angeles-Beltrán, Laura Nadxieli Palacios-Grijalva, Nahí Adriana Guerra-Navarro
Jazyk: angličtina
Rok vydání: 2011
Předmět:
Zdroj: Molecules, Vol 16, Iss 8, Pp 6561-6576 (2011)
Druh dokumentu: article
ISSN: 1420-3049
DOI: 10.3390/molecules16086561
Popis: A comparison was made of the effectiveness of the functionalization reactions of pentacyclo[5.4.0.02,6.03,10.05,9]undecane-8,11-dione (PCU) using sulphated zirconia in protection-deprotection reactions and Mg/Al hydrotalcite in a cyanosilylation reaction, under classical thermal conditions and imposing microwave radiation; improved yields and reaction times were considered.
Databáze: Directory of Open Access Journals