Flash Vacuum Pyrolysis of 2,5-Diphenyloxazole
| Autor: | Constantin Draghici, Dan Mihaiescu, Daniela Istrati, Mircea D. Banciu |
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| Jazyk: | angličtina |
| Rok vydání: | 2000 |
| Předmět: | |
| Zdroj: | Molecules, Vol 5, Iss 8, Pp 1004-1010 (2000) |
| Druh dokumentu: | article |
| ISSN: | 1420-3049 |
| DOI: | 10.3390/50801004 |
| Popis: | FVP of the title oxazole (1) at 1000oC and 0.5 mm Hg afforded a complex reaction mixture containing benzonitrile, phenylacetonitrile, biphenyl, diphenylmethane, fluorene, o-benzylbenzonitrile (major product, 22%), phenanthrene, anthracene, 9,10-anthraquinone, 2-phenylindole and 3-phenylindole. A radical and carbene mechanism was suggested in order to rationalize the formation of the reaction products. |
| Databáze: | Directory of Open Access Journals |
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