Use of Rubber Process Analyzer for Characterizing the Molecular Weight Parameters of Natural Rubber

Autor: Tianming Gao, Ruihong Xie, Linghong Zhang, Hongxing Gui, Maofang Huang
Jazyk: angličtina
Rok vydání: 2015
Předmět:
Zdroj: International Journal of Polymer Science, Vol 2015 (2015)
Druh dokumentu: article
ISSN: 1687-9422
1687-9430
55460895
DOI: 10.1155/2015/517260
Popis: The aim of this work is to introduce a simple and rapid method for characterizing the molecular weight parameters and other molecular structure parameters of natural rubber (NR) using a rubber process analyzer (RPA). In this work, NR of different molecular weights was prepared by milling. Molecular weight parameters were measured by gel permeation chromatography coupled with laser light scattering (GPC-LLS) for comparison with RPA results. It was verified that increasing of milling time leads to a decrease of the number-average molecular weight (M-n), weight-average molecular weight (M-w), and molecular weight distribution (MWD). The dynamic and rheological properties were evaluated on RPA by tests of strain sweep, frequency sweep, and stress relaxation. These results were used to characterize the average molecular weight, MWD, and viscosity of NR and were found to agree with those from GPC-LLS. This convenient and rapid technology for characterizing NR molecular weight parameters would be especially useful in the elastomer industry.
Databáze: Directory of Open Access Journals
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