N,N′-Di-tert-butyl-N′′-(2-chloroacetyl)phosphoric triamide
| Autor: | Mehrdad Pourayoubi, Behrouz Elahi, Masood Parvez |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2011 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 67, Iss 11, Pp o2848-o2848 (2011) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S1600536811040773 |
| Popis: | The P atom in the title molecule, C10H23ClN3O2P, has a distorted tetrahedral coordination. In the C(O)NHP(O) unit, which has syn-oriented phosphoryl and N—H groups, the P—N bond of 1.703 (2) Å is longer and the O—P—N angle of 103.86 (7)° is contracted compared with the respective values in the two P(O)NHC(CH3)3 units [P—N = 1.632 (2) and 1.624 (2) Å; O—P—N = 116.80 (8) and 115.32 (8)°]. In the crystal, each molecule is hydrogen bonded to two adjacent molecules via N—H...O hydrogen bonds, forming a linear sequence of alternating R22(8) and R22(12)/R21(6)-fused rings along [010]. The O atom of the carbonyl group acts as a double H-atom acceptor. |
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