catena-Poly[[triphenyltin(IV)]-μ-2-(2-picolinoylhydrazono)propanoato-κ2O1:O2]

Autor: Jichun Cui, Yanling Qiao, Longhua Ding, Handong Yin
Jazyk: angličtina
Rok vydání: 2009
Předmět:
Zdroj: Acta Crystallographica Section E, Vol 65, Iss 11, Pp m1313-m1313 (2009)
Druh dokumentu: article
ISSN: 16005368
1600-5368
DOI: 10.1107/S1600536809039981
Popis: In the title polymeric coordination compound, [Sn(C6H5)3(C9H8N3O3)]n, the SnIV atom is in a distorted trigonal-bipyramidal geometry, being coordinated by two O atoms from two 2-(2-picolinoylhydrazono)propanoate ligands and three phenyl groups. Adjacent Sn atoms are bridged by the 2-(2-picolinoylhydrazono)propanoate ligand through one carbonyl O atom and one carboxylate O atom, forming a chain structure propagating parallel to [100]. An intramolecular N—H...O hydrogen bond is observed.
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