Comparative assessment of structural, magnetic and impedance properties of xLaMnO3-(1-x)BiFeO3 solid solutions
| Autor: | Kaur Shubhpreet, Paswan Manikant |
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| Jazyk: | angličtina |
| Rok vydání: | 2024 |
| Předmět: | |
| Zdroj: | Processing and Application of Ceramics, Vol 18, Iss 3, Pp 307-313 (2024) |
| Druh dokumentu: | article |
| ISSN: | 1820-6131 2406-1034 |
| DOI: | 10.2298/PAC2403307L |
| Popis: | BiFeO3 (BFO) is extensively researched due to its lead-free composition, high ordering temperature, remarkable polarization and useful electric and magnetic switching mechanism for data storage devices. On the other hand, the superexchange ordered system of LaMnO3 (LMO) is well-suited for fuel cells. This study examines the structural, magnetic and impedance properties of xLaMnO3-(1-x)BiFeO3 solid solutions (x = 0.05, 0.10 and 0.20) prepared using the solid state reaction method and sintering. X-ray diffraction technique confirmed single phase material with the hexagonal structure and R3c symmetry. The vibrating sample magnetometer showed the change from antiferromagnetic behaviour of BFO to weak ferromagnetic behaviour of BFO/LMO ceramics and maximum remnantmagnetization of 0.206 emu/g for x = 0.10. The superexchange interactions are responsible for this magnetic behaviour. Impedance analysis was used to investigate the dielectric relaxation and the negative temperature coefficient of resistance. |
| Databáze: | Directory of Open Access Journals |
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