Crystal structure of 1,1′,2,2′,4,4′-hexaisopropylmagnesocene

Autor: Nico Bachmann, Lisa Wirtz, Bernd Morgenstern, Carsten Müller, André Schäfer
Jazyk: angličtina
Rok vydání: 2022
Předmět:
Zdroj: Acta Crystallographica Section E: Crystallographic Communications, Vol 78, Iss 3, Pp 287-290 (2022)
Druh dokumentu: article
ISSN: 2056-9890
20569890
DOI: 10.1107/S2056989022001189
Popis: The title compound, 3Cp2Mg or [Mg(C14H23)2], was synthesized from the corresponding triisopropylcyclopentadiene by treatment with n-butyl-sec-butylmagnesium. The structural characterization by single-crystal X-ray diffraction revealed that the compound crystallizes in the triclinic space group P\overline{1} with half a molecule per asymmetric unit and a staggered arrangement of the cyclopentadienide ligands.
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