Synthesis of nano magnetic supported NHC-palladium and investigation of its applications as a catalyst in the Mizoroki-Heck cross-coupling reaction in H2O

Autor: Razieh Ghavidel Kalishomi, Shahnaz Rostamizadeh, Fatemeh Nouri, Ali Khazaei
Jazyk: angličtina
Rok vydání: 2020
Předmět:
Zdroj: Heliyon, Vol 6, Iss 9, Pp e04946- (2020)
Druh dokumentu: article
ISSN: 2405-8440
DOI: 10.1016/j.heliyon.2020.e04946
Popis: The unique properties of N-heterocyclic carbenes (NHCs) as an effective ligand for palladium catalytic centers have recently found much attention. In this work, Fe3O4 nanoparticle supported palladium(II)–N-heterocyclic carbene catalyst was successfully designed, synthesized and characterized by various methods. The activity of the catalyst was evaluated in the Mizoroki-Heck cross-coupling reaction in which the desired products were obtained in high yield in H2O as a green solvent. The reaction was carried out in short reaction times using low amounts of the catalyst. Moreover, the catalyst was easily separated from the reaction media and reused for 5 cycles.
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