Crystal structure of N′-[(1E)-1-(6-methyl-2,4-dioxo-3,4-dihydro-2H-pyran-3-ylidene)ethyl]benzenesulfonohydrazide
| Autor: | Jonnie N. Asegbeloyin, Oguejiofo T. Ujam, Chizoba M. Ngige, Valentine I. Onwukeme, Tania Groutso |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2014 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 70, Iss 11, Pp o1179-o1180 (2014) |
| Druh dokumentu: | article |
| ISSN: | 1600-5368 16005368 |
| DOI: | 10.1107/S1600536814022648 |
| Popis: | In the title compound, C14H14N2O5S, the molecule exists in the enamine (C=C—NH) tautomeric form. The hydrazone fragment derived from the 3-acetyl-4-hydroxy-6-methyl-2H-pyran-2-one moiety is approximately planar, with a maximum deviation of 0.1291 (11) Å for the N atom bound to the S atom of the benzensulfonohydrazide group. The latter adopts a gauche conformation relative to the hydrazone N—N bond, with an N—N—S angle of 113.54 (10)°. There is an intramolecular N—H...O=C hydrogen bond that stabilizes the tautomeric form. In the crystal, molecules are linked by N—H...O=C hydrogen bonds into chains extending parallel to [100]. |
| Databáze: | Directory of Open Access Journals |
| Externí odkaz: |
|