Amino Acid-Functionalized Polyfluorenes: A Class of Ultra-Sensitive Fluorescent Sensors Favoring Cr2O72−
Autor: | Wanyi Zhang, Hui Li, Yu Li, Lei Cao, Li Sheng, Ge Zhang, Shuai Chen |
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Jazyk: | angličtina |
Rok vydání: | 2023 |
Předmět: | |
Zdroj: | Engineering Proceedings, Vol 48, Iss 1, p 52 (2023) |
Druh dokumentu: | article |
ISSN: | 2023-1490 2673-4591 |
DOI: | 10.3390/CSAC2023-14909 |
Popis: | Conjugated polymers (CPs) are an intriguing material with which to build fluorescent Cr2O72− sensors with excellent sensitivity, but they often lack specific recognition groups. In this study, several typical amino acids with N and O atom-identifying groups were incorporated into fluorene, and then six polyfluorene derivatives were synthesized using electrochemical polymerization. Compared to other cations and anions, all of these amino acid-functionalized polyfluorenes have good selectivity towards Cr2O72− and enable ultra-trace responses with detection thresholds at pM or even fM level. |
Databáze: | Directory of Open Access Journals |
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