| Autor: |
Nathan C. Harms, Takahiro Matsuoka, Subhasis Samanta, Amanda J. Clune, Kevin A. Smith, Amanda V. Haglund, Erxi Feng, Huibo Cao, Jesse S. Smith, David G. Mandrus, Heung-Sik Kim, Zhenxian Liu, Janice L. Musfeldt |
| Jazyk: |
angličtina |
| Rok vydání: |
2022 |
| Předmět: |
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| Zdroj: |
npj 2D Materials and Applications, Vol 6, Iss 1, Pp 1-8 (2022) |
| Druh dokumentu: |
article |
| ISSN: |
2397-7132 |
| DOI: |
10.1038/s41699-022-00313-9 |
| Popis: |
Abstract van der Waals solids are ideal platforms for the discovery of new states of matter and emergent properties under external stimuli. Under pressure, complex chalcogenides like MPS3 (M = Mn, Ni, Co, V) host sliding and structural transitions, insulator-to-metal transitions, the possibility of an orbitally-selective Mott state, piezochromism, and superconductivity. In this work, we bring together diamond anvil cell techniques, infrared and Raman scattering spectroscopies, and X-ray diffraction with a detailed symmetry analysis and first-principles calculations to uncover a series of high-pressure phases in NiPS3. Remarkably, we find five different states of matter between ambient conditions and 39 GPa—quite different than in the other MPS3 materials. Even more strikingly, infrared spectroscopy and X-ray diffraction combined with a symmetry analysis reveal both metallicity and loss of the inversion center above ~23 GPa suggesting that NiPS3 may be a polar metal with a P3m1 space group under these conditions and P1 symmetry under maximum compression. In addition to identifying a candidate polar metal ripe for further inquiry, we suggest that pressure may tune other complex chalcogenides into this elusive state. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
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