| Autor: |
Hossein Roohollahi, Marzieh Hamidzadeh, Fereydoon Yaripour, Solmaz Shifteh |
| Jazyk: |
angličtina |
| Rok vydání: |
2023 |
| Předmět: |
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| Zdroj: |
Catalysis Communications, Vol 183, Iss , Pp 106782- (2023) |
| Druh dokumentu: |
article |
| ISSN: |
1873-3905 |
| DOI: |
10.1016/j.catcom.2023.106782 |
| Popis: |
Boron was implemented to promote the catalytic behavior of H-ZSM-5 zeolite in methanol to propylene (MTP) process. A series of crystalline borosilicates with different boron contents were synthesized using a seed-assisted hydrothermal technique and characterized well. Results revealed that increasing the boron coefficient improved lifetime and propylene productivity of zeolite by 20 and 24%, respectively. Hierarchal micro-mesoporosity and the distribution of acid sites made a substantial contribution to H-[B]-ZSM-5 performance in MTP. Boron played a significant role in tuning the acidity of the catalyst and improved its stability by controlling the formation of heavy hydrocarbons (C5+) in the MTP reaction. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
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Full Text from ScienceDirect