(7-Chloro-2-oxo-2H-chromen-4-yl)methyl pyrrolidine-1-carbodithioate

Autor: O. Kotresh, H. C. Devarajegowda, Arunkumar Shirahatti, K. Mahesh Kumar, N. M. Mahabhaleshwaraiah
Jazyk: angličtina
Rok vydání: 2013
Předmět:
Zdroj: Acta Crystallographica Section E, Vol 69, Iss 11, Pp o1684-o1685 (2013)
Druh dokumentu: article
ISSN: 16005368
1600-5368
DOI: 10.1107/S1600536813028080
Popis: In the title compound, C15H14ClNO2S2, the 2H-chromene ring system is essentially planar, with a maximum deviation of 0.0133 (10) Å. Three C atoms and their attached H atoms of the pyrrolidine ring are disordered [occupany ratio 0.874 (7):0.126 (7)] with both disorder components adopting a twisted conformation. The dihedral angle between the 2H-chromene ring system and the major occupancy component of the pyrrolidine ring is 89.45 (7)°. In the crystal, inversion dimers linked by pairs of C—H...S and C—H...O interactions generate R22(24) and R22(10) loops, respectively. Further C—H...O hydrogen bonds link the dimers into [100] chains. C—H...π interactions also occur and there is very weak π–π stacking [interplanar spacing = 3.650 (5) Å; centroid–centroid distance = 4.095 (7) Å] between inversion-related chlorobenzene rings.
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