The role of modified manganese perovskite oxide for selective oxidative dehydrogenation of ethane: Not only selective H2 combustion but also ethane activation

Autor: Fang Jin, Xiaojie Cheng, Tianyu Wan, Jianhong Gong, Tingyu Liang, Guiying Wu
Jazyk: angličtina
Rok vydání: 2022
Předmět:
Zdroj: Catalysis Communications, Vol 172, Iss , Pp 106531- (2022)
Druh dokumentu: article
ISSN: 1873-3905
DOI: 10.1016/j.catcom.2022.106531
Popis: To break through the thermodynamic reaction limitation of ethane dehydrogenation to ethylene, the oxidative dehydrogenation in the presence of O2 and chemical looping oxidative dehydrogenation has been investigated with the oxygen storage oxide compound. LaMnO3 perovskite catalysts with large specific surface areas were prepared using citric acid-nitrate combustion. The oxygen vacancies and M4+ contents in the catalysts were improved by doping LaMnO3 as the active sites. The experimental results show that the catalyst not only promotes ethane dehydrogenation through selective hydrogen combustion but also promotes ethane conversion through activation of CH. The catalyst exhibits good stability in oxidative dehydrogenation reaction.
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