Bis(μ-biphenyl-2,2′-dicarboxylato)bis[aqua(2,2′-bipyridine)cadmium(II)]
| Autor: | Pei-Xi Lin, Yan Cheng, Yu-Lian Mai, Zhe An |
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| Jazyk: | angličtina |
| Rok vydání: | 2010 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 66, Iss 6, Pp m637-m637 (2010) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S1600536810016387 |
| Popis: | In the centrosymmetric dinuclear molecule of the title compound, [Cd2(C14H8O4)2(C10H8N2)2(H2O)2], the Cd2+ ion is coordinated by three O atoms from two different diphenyldicarboxylate (dpa) ligands (one O,O′-bidentate and one monodentate), a chelating bipyridine ligand and a water molecule, generating an extremely distorted trigonal-prismatic (or irregular) CdN2O4 coordination geometry for the metal ion. The bridging ligands generate an 18-membered ring, which is stabilized by two pairs of intramolecular O—H...O hydrogen bonds. |
| Databáze: | Directory of Open Access Journals |
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