Synthesis of Cycle B Functionalized Derivatives of (+)-Larixol
| Autor: | Alexandru Ciocarlan, Lidia Lungu, Svetlana Blaja, Sergiu Shova, Aculina Aricu |
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| Jazyk: | angličtina |
| Rok vydání: | 2024 |
| Předmět: | |
| Zdroj: | Chemistry Journal of Moldova: General, Industrial and Ecological Chemistry, Vol 19, Iss 1, Pp 69-75 (2024) |
| Druh dokumentu: | article |
| ISSN: | 1857-1727 2345-1688 |
| DOI: | 10.19261/cjm.2024.1156 |
| Popis: | The main purpose of this research was the synthesis of highly functionalized derivatives of (+)-larixol by combination of classical and nonconventional method, like dye-sensitized photooxidation with preservation of outside chain. As a result, a series of four new cycle B derivatives of (+)-larixol were obtained, including products of photooxidative dehydrogenation and [2+4] cycloaddition of singlet oxygen, compounds 7 and 8, respectively. The structure of all synthesized compounds was fully confirmed by spectral method (IR, 1H and 13C NMR) and for compound 8 containing endoperoxide functional group, additionally by single crystal X-ray diffraction analysis. |
| Databáze: | Directory of Open Access Journals |
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