Synthesis and Magnetic Properties of a Copper Cube: [Cu4(OH)4(C16H18N2)4]4+ (ClO4)4 C3H6O [C16H18N2=(E)‐1,6‐[Di(pyridin‐4‐yl)hex‐3‐ene]

Autor:	Dr. M. John Plater, Amara Darr, Catriona Crawford, Craig Murray, Struan Simpson, Prof. William T. A. Harrison, Prof. Juan M. Clemente‐Juan
Jazyk:	angličtina
Rok vydání:	2019
Předmět:	copper(II) perchlorate magnetic properties Jahn-Teller distortion clusters Chemistry QD1-999
Zdroj:	ChemistryOpen, Vol 8, Iss 9, Pp 1204-1208 (2019)
Druh dokumentu:	article
ISSN:	2191-1363 20190026
DOI:	10.1002/open.201900260
Popis:	Abstract The synthesis of a Cu4(OH)4 cube which is coordinated by four molecules of the dipyridyl ligand 1,6‐[di(pyridin‐4‐yl)hex‐3‐ene] is reported. This compound has a trans double bond which restricts the conformational freedom of the ligand and favours coordination within a unique copper cube. The structure was solved by an X‐Ray single crystal structure determination and low temperature magnetic susceptibility measurements examined its magnetic properties. The cube classification corresponds to the type I classification of Mergehenn and Haase and the short/long distribution of Cu ⋅⋅⋅ Cu separations in the cube as defined by Ruiz. The magnetic susceptibility measurements show paramagnetic behaviour down to 50 K but below this the copper cube shows weak ferromagnetic exchange interactions. The low temperature magnetic susceptibility characteristics are examined in detail then modelled and compared to other similar Cu4O4 copper cubes.
Databáze:	Directory of Open Access Journals
Externí odkaz:	https://doaj.org/article/872b485c219e468cb0ec113615e77b48 Zobrazit plný text záznamu View record in DOAJ Plný text ve formátu PDF Plný text ve formátu HTML
Nepřihlášeným uživatelům se plný text nezobrazuje	K zobrazení výsledku je třeba se přihlásit.