(1,10-Phenanthroline-κ2N,N′)bis(2,2,6,6-tetramethylheptane-3,5-dionato-κ2O,O′)nickel(II)
| Autor: | Branko Kaitner, Krešo Mesarek, Ernest Meštrović |
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| Jazyk: | angličtina |
| Rok vydání: | 2008 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 64, Iss 1, Pp m230-m231 (2008) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S160053680706672X |
| Popis: | The title compound, [Ni(C11H19O2)2(C12H8N2)], was obtained from the reaction of bis(2,2,6,6-tetramethylheptane-3,5-dionato)nickel(II), [Ni(dpm)], and 1,10-phenanthroline (phen). The NiII ion is coordinated by four O atoms from two dpm ligands and two N atoms from a phen ligand in a slightly distorted octahedral environment. The methyl C atoms of two of the tert-butyl groups are disordered over two sites, having approximate occupancies of 0.85 and 0.15 for the two components. In the crystal structure, there are no direction-specific interactions. Thermal studies showed that the title complex is stable to 623 K. |
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