Autor: |
Laura G. Sarbu, Henning Hopf, Peter G. Jones, Lucian M. Birsa |
Jazyk: |
angličtina |
Rok vydání: |
2014 |
Předmět: |
|
Zdroj: |
Beilstein Journal of Organic Chemistry, Vol 10, Iss 1, Pp 2550-2555 (2014) |
Druh dokumentu: |
article |
ISSN: |
1860-5397 |
DOI: |
10.3762/bjoc.10.266 |
Popis: |
An addition/elimination sequence of selenium halides to pseudo-geminally bis(acetylene) substituted [2.2]paracyclophanes leads to new bridges with an endo-exo-diene substructure. The reactions have been found to be sensitive to the substitution of the ethynyl group. The formation of dienes with a zig-zag configuration is related to that observed for non-conjugated cyclic diynes of medium ring size. |
Databáze: |
Directory of Open Access Journals |
Externí odkaz: |
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