Effect of Electrodeposition Time on Absorptance, Roughness and Thermal Stability of Black Chromium Absorbing Surfaces

Autor: João Victor Furtado Frazão de Medeiros, Aline da Silva Oliveira, Gabriela Oliveira Galvão, Ithyara Dheylle Machado de Medeiros, Kelly Cristiane Gomes
Jazyk: angličtina
Rok vydání: 2022
Předmět:
Zdroj: Materials Research, Vol 25 (2022)
Druh dokumentu: article
ISSN: 1516-1439
1980-5373
DOI: 10.1590/1980-5373-mr-2021-0484
Popis: Abstract Solar thermal energy is one of the ways of using solar radiation that can be applied to meet the energy needs for heating. To achieve efficient photothermal conversion, selective surfaces are applied to solar collectors to absorb more radiation and minimize heat loss. The present work produced absorber surfaces from black chromium electrodeposition on stainless steel substrate, the main parameter evaluated was the deposition time and its effect on optical and morphological properties. In this sense, the techniques of characterization UV-Vis-NIR Spectroscopy, Infrared Spectroscopy, X-Ray Diffraction, Optical Profilometry and Thermogravimetric analysis were used. It was observed a great influence of the electrodeposition time in the absorptance of the films, where films with deposition times of 2 to 10 minutes obtained absorptances greater than 92%. The metallic Cr phase was identified in the films, and it is estimated that chromium oxides may have been formed in the amorphous form. With increasing time, the roughness oscillated due to the constant nucleation of chromium throughout the process. Furthermore, a 5% mass loss indicates good thermal stability of the film up to 400 °C.
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