Schmidt Reaction of E-3-Benzylidenechromanones and E-3-Benzylidenethiochromanones
| Autor: | Tapas K. Mandal, Rammohan Pal, Rina Mondal, Sankar P. Dey, Asok K. Mallik |
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| Jazyk: | angličtina |
| Rok vydání: | 2013 |
| Předmět: | |
| Zdroj: | Journal of Chemistry, Vol 2013 (2013) |
| Druh dokumentu: | article |
| ISSN: | 2090-9063 2090-9071 |
| DOI: | 10.1155/2013/392128 |
| Popis: | On treatment with NaN3/c. H2SO4-HOAc or NaN3/TFA, E-3-benzylidenechromanones are mostly converted to E-β-aminobenzylidenechromanones while E-3-benzylidenethiochromanones are converted to 3-benzoylthiochromones. A structurally new type of product has been isolated for the reaction of E-3-benzylidene-4′-methoxychromanone with NaN3/TFA. Mechanistic paths have been suggested for formation of the products. |
| Databáze: | Directory of Open Access Journals |
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