Binding and reactivity in deep cavitands based on resorcin[4]arene
| Autor: | Manuel Petroselli, Yong-Qing Chen, Julius Rebek, Jr., Yang Yu |
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| Jazyk: | angličtina |
| Rok vydání: | 2021 |
| Předmět: | |
| Zdroj: | Green Synthesis and Catalysis, Vol 2, Iss 2, Pp 123-130 (2021) |
| Druh dokumentu: | article |
| ISSN: | 2666-5549 85782777 |
| DOI: | 10.1016/j.gresc.2021.03.004 |
| Popis: | A widely used class of synthetic receptors are resorcin[4]arene-based cavitands. A collection of the most representative studies in this field is reported here, from organic-soluble receptors to those that are water-soluble. Intermolecular forces involved in complex formation – hydrogen bonds, halogen bonds and solvophobic interactions – are discussed with emphasis on the relationship between guest conformation and reactivity in the cavity. The applications of hosts as reaction vessels, chaperones, templates and protecting groups in organic and aqueous media are explored, highlighting how synthetic receptors are modern tools to explore the behavior of molecules in confined spaces. |
| Databáze: | Directory of Open Access Journals |
| Externí odkaz: |
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