Synthesis and crystal structure of a new 2D supramolecular Cd(II) complex with 1-phenyl-3-methyl-4-benzoyl-5-pyrazolone ligand
| Autor: | Zhang Li-Ping, Deng Shu-E, Wang Xue-Dong |
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| Jazyk: | angličtina |
| Rok vydání: | 2015 |
| Předmět: | |
| Zdroj: | Main Group Metal Chemistry, Vol 38, Iss 1-2, Pp 37-42 (2015) |
| Druh dokumentu: | article |
| ISSN: | 0792-1241 2191-0219 |
| DOI: | 10.1515/mgmc-2014-0044 |
| Popis: | A new Cd(II) complex, [Cd(PMBP)2(CH3OH)2] (PMBP = 1-phenyl-3-methyl-4-benzoyl-5-pyrazolone), has been synthesized and characterized by elemental analysis, IR spectroscopy, thermal gravimetric analysis, fluorescence analysis, and X-ray single-crystal diffraction. In the complex, a slightly distorted octahedral geometry of cadmium ion is coordinated by six oxygen atoms, and the cadmium ion locates in the center position. The complex is a monomeric species, which is extended into 2D supramolecular architecture by strong intermolecular hydrogen bonds. Moreover, the intramolecular hydrogen bonds and C-H···π interactions are also found in the complex so that the 2D supramolecular network is consolidated. |
| Databáze: | Directory of Open Access Journals |
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